I don't recommend taking the charcoal canister off, but its your car and you can do what you want. The only thing it will effect is gas mileage and emissions output.
The big metal line that is near the firewall is the fuel vapor feed from the tank, you must block this off if you remove the charcoal canister. The little vacuum line that goes to the BVSV can just be plugged off. The metal line that is at the bottom of the canister that goes into a hole in the body is a fresh air feed, nothing to block off there.
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